A porous silicon-carbon anode with high overall capacity on carbon fiber current collector

被引:74
作者
Guo, Juchen [1 ]
Sun, Ann [1 ]
Wang, Chunsheng [1 ]
机构
[1] Univ Maryland, Dept Chem & Biomol Engn, College Pk, MD 20742 USA
关键词
Silicon anode; Porous; Carbon fiber; Lithium-ion battery; LITHIUM STORAGE; COATED SILICON; ION BATTERIES; NANOPARTICLES; PERFORMANCE; COMPOSITE;
D O I
10.1016/j.elecom.2010.05.006
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A porous silicon-carbon anode on a lightweight carbon fiber current collector is reported here for lithium-ion batteries. This Si-C anode was synthesized through a one-step carbonization of a Si-poly(acrylonitrile-co-methyl acrylate) precursor, which was directly deposited on a carbon fiber mat. The carbon fiber curent collector allows higher loading of active materials, resulting in high energy to mass and area ratios. The obtained Si-C electrode demonstrated superior overall capacity, cyclability, and rate capacity. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:981 / 984
页数:4
相关论文
共 17 条
[11]   Silicon nanoparticles-graphene paper composites for Li ion battery anodes [J].
Lee, Jeong K. ;
Smith, Kurt B. ;
Hayner, Cary M. ;
Kung, Harold H. .
CHEMICAL COMMUNICATIONS, 2010, 46 (12) :2025-2027
[12]   Enhanced cycle life of Si anode for Li-ion batteries by using modified elastomeric binder [J].
Liu, WR ;
Yang, MH ;
Wu, HC ;
Chiao, SM ;
Wu, NL .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (02) :A100-A103
[13]  
Magasinski A, 2010, NAT MATER, V9, P353, DOI [10.1038/NMAT2725, 10.1038/nmat2725]
[14]   Highly reversible lithium storage in spheroidal carbon-coated silicon nanocomposites as anodes for lithium-ion batteries [J].
Ng, See-How ;
Wang, Jiazhao ;
Wexler, David ;
Konstantinov, Konstantin ;
Guo, Zai-Ping ;
Liu, Hua-Kun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (41) :6896-6899
[15]   Cage-like carbon nanotubes/Si composite as anode material for lithium ion batteries [J].
Shu, J ;
Li, H ;
Yang, RZ ;
Shi, Y ;
Huang, XJ .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (01) :51-54
[16]   A high performance silicon/carbon composite anode with carbon nanofiber for lithium-ion batteries [J].
Si, Q. ;
Hanai, K. ;
Ichikawa, T. ;
Hirano, A. ;
Imanishi, N. ;
Takeda, Y. ;
Yamamoto, O. .
JOURNAL OF POWER SOURCES, 2010, 195 (06) :1720-1725
[17]   Lithium insertion in carbon-silicon composite materials produced by mechanical milling [J].
Wang, CS ;
Wu, GT ;
Zhang, XB ;
Qi, ZF ;
Li, WZ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (08) :2751-2758