RADICAL FORMATION IN SALTS OF PYRIMIDINES .3. CYTOSINE.H2O CRYSTALS

被引:54
作者
FLOSSMANN, W [1 ]
WESTHOF, E [1 ]
MULLER, A [1 ]
机构
[1] UNIV REGENSBURG, INST BIOPHYS & PHYS BIOCHEM, D-8400 REGENSBURG, FED REP GER
关键词
D O I
10.1080/09553007614551081
中图分类号
Q [生物科学];
学科分类号
07 ; 0710 ; 09 ;
摘要
The radicals produced by X-irradiation at 77.degree. K and at 300.degree. K in cytosine monohydrate crystals were analyzed by ESR spectroscopy. Identified at 77.degree. K were the anion radical and the cation radical of the cytosine molecule, together with the radical resulting from H-abstraction from the nitrogen N1. Irradiation at 300.degree. K produces radicals resulting from H-addition at 3 different positions of the cytosine molecule. These are the C5-addition radical, the C6-addition radical and the O2-addition radical.
引用
收藏
页码:301 / 315
页数:15
相关论文
共 19 条
[11]   ESR AND ENDOR OF FREE-RADICALS IN X-IRRADIATED BARBITURIC ACID [J].
HUTTERMANN, J ;
SCHMIDT, G ;
WEYMANN, D .
JOURNAL OF MAGNETIC RESONANCE, 1976, 21 (02) :221-234
[12]   CRYSTAL STRUCTURE OF CYTOSINE MONOHYDRATE [J].
JEFFREY, GA ;
KINOSHITA, Y .
ACTA CRYSTALLOGRAPHICA, 1963, 16 (01) :20-&
[13]   NEW INVESTIGATIONS OF CYTOSINE AND ITS MONOHYDRATE [J].
MCCLURE, RJ ;
CRAVEN, BM .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (JUN15) :1234-1238
[14]   ELECTRON-SPIN RESONANCE STUDY OF N1-SUBSTITUTED THYMINE PI-CATION RADICALS [J].
SEVILLA, MD .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (17) :1898-1901
[16]   RADICAL FORMATION IN SALTS OF PYRIMIDINES .2. CYTOSINE.HCL CRYSTALS [J].
WESTHOF, E ;
FLOSSMANN, W ;
MULLER, A .
INTERNATIONAL JOURNAL OF RADIATION BIOLOGY, 1975, 28 (05) :427-438
[17]   INDO ANALYSIS OF IMIDAZOLE ANION AND HYDROGEN ADDITION RADICALS [J].
WESTHOF, E ;
FLOSSMANN, W .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) :6622-6623
[18]  
WESTHOF E, 1976, Z NATURFORSCH C, V31, P371
[19]  
ZEHNER H, IN PRESS