活性白土对模拟油脂中β-胡萝卜素和叶绿素的吸附动力学研究(英文)

被引:7
作者
童军茂
武占省
孙喜房
徐小琳
李春
机构
[1] KeyLaboratoryforGreenProcessingofChemicalEngineeringofXinjiangBingtuan,ShiheziUniversity
关键词
acid-activated bentonite; pigment; model oil solution; adsorption kinetics;
D O I
暂无
中图分类号
O647.31 [吸附理论];
学科分类号
070304 ; 081704 ;
摘要
The textural properties of acid-activated bentonite(AAB),which were prepared using four different concentrations of sulfuric acid,were analyzed by adsorption-desorption isotherm of nitrogen using an automated specific surface area and porosity analyzer.The total pore volume,specific surface area and average pore diameter of these four kinds of AAB show a regular changing trend,increasing first and then decreasing,the optimum of which can be achieved at a sulfuric acid concentration of 25%(sample A25).The kinetic analysis of the adsorption ofβ-carotene and chlorophyll in model oil solutions,namely,xylene and edible oil solution,has been investigated by using AAB.Experimental results indicated that the adsorption data fit the pseudo-second-order model well.The whole adsorption process of the two pigments on AAB was divided basically into two parts:the initial adsorption of pigments was rapid in the first 10 min,followed by a slower adsorption process till equilibrium was attained at 60 min.In addition,the amount and rate of adsorption on A25 increase synchronously with the initial pigment concen- tration and temperature.The results showed that the adsorption kinetics behavior of AAB with respect to the pig- ments is not influence by the xylene and edible oil solution.
引用
收藏
页码:270 / 276
页数:7
相关论文
共 8 条
[1]   Adsorption kinetics of β-carotene from soy oil using regenerated clay [J].
Ma, MH ;
Lin, CI .
SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 39 (03) :201-209
[2]   Pseudo-second order model for sorption processes [J].
Ho, YS ;
McKay, G .
PROCESS BIOCHEMISTRY, 1999, 34 (05) :451-465
[3]   Cottonseed oil bleaching by acid-activated montmorillonite [J].
Falaras, P ;
Kovanis, I ;
Lezou, F ;
Seiragakis, G .
CLAY MINERALS, 1999, 34 (02) :221-232
[4]   Bleaching kinetics of sunflowerseed oil [J].
Topallar, H .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1998, 75 (04) :531-533
[5]   Industrial applications of acid-treated clays as catalysts [J].
Chitnis, SR ;
Sharma, MM .
REACTIVE & FUNCTIONAL POLYMERS, 1997, 32 (01) :93-115
[6]  
Smectites: the relationship between their properties and isomorphic substitution[J] . D. Siguín,S. Ferreira,L. Froufe,F. García.Journal of Materials Science . 1994 (16)
[7]   CHLOROPHYLL ADSORPTION ON ACID-ACTIVATED CLAY [J].
GULER, C ;
TUNC, F .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (09) :948-950
[8]  
β-Carotene adsorption on acid-activated montmorillonite[J] . Journal of the American Oil Chemists Society . 1988 (5)