福建永定大坪铌钽矿化花岗斑岩体的流体演化对铌钽富集的制约

被引:5
作者
刘永超 [1 ]
李建康 [1 ]
邹天人 [1 ]
江善元 [2 ]
丁欣 [3 ]
王娴 [3 ]
机构
[1] 中国地质科学院矿产资源研究所
[2] 中国冶金地质总局第二地质勘察院
[3] 中国地质大学地球科学与资源学院
关键词
流体包裹体; 熔体包裹体; 铌钽; 大坪斑岩体; 福建永定;
D O I
暂无
中图分类号
P618.79 [铌]; P618.86 [钽];
学科分类号
0709 ; 081803 ;
摘要
福建永定大坪铌钽矿化花岗斑岩体位于永定县城南部的大石凹-蓝地火山喷发盆地,对斑岩型铌钽矿床的产出具有重要的指示意义。本文通过岩相学、显微测温和激光拉曼等实验对大坪岩体ZK10001和ZK10401钻孔不同深度岩石样品中的流体和熔体包裹体进行了研究,试图揭示岩体的熔体-流体演化过程,分析铌钽等成矿元素的富集机制。观测结果表明,大坪岩体主要发育气液两相盐水溶液包裹体和硅酸盐熔体包裹体。流体包裹体均一温度集中在175~225℃,盐度集中在3%~7%NaCleq,密度集中在0.75~0.95g/cm3,成矿流体主要为中低温、低盐度和低密度的流体,总体属于H2O-NaCl体系。熔体包裹体主要分布于石英斑晶雪球结构的环带中,含有钠长石、石英和钽铁矿等子矿物。熔体包裹体完全均一温度较高,能够代表早期原始岩浆的组成。研究表明,大坪岩体的原始岩浆富铌钽等成矿元素和碱性组分,大坪岩体的铌钽矿化是岩浆高度分异的产物,铌钽的富集过程经历了斑晶阶段和基质阶段等两阶段结晶分异过程:在早期斑晶结晶阶段,少量铌钽矿物与斑晶一起结晶,并被斑晶包裹;岩浆演化晚期发生流体出溶现象,但未分异出大量流体,F等挥发分促进了铌钽在结晶残余熔体中富集,并在基质间隙中沉淀。大坪矿化岩体的存在指示出斑岩型铌钽矿床存在的可能性。
引用
收藏
页码:1052 / 1065
页数:14
相关论文
共 39 条
[11]  
流体包裹体[M]. 科学出版社 , 卢焕章等著, 2004
[12]  
Differentiated rare-element mineralization in an ongonite–topazite composite dike at the Xianghualing tin district, Southern China: An electron-microprobe study on the evolution from niobium–tantalum-oxides to cassiterite[J] . Fang-Fang Huang,Ru-Cheng Wang,Lei Xie,Jin-Chu Zhu,Saskia Erdmann,Xu-Dong Che,Rong-Qing Zhang.Ore Geology Reviews . 2014
[13]  
Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry[J] . Anna Gioncada,Paolo Orlandi,Luigina Vezzoli,Ricardo H. Omarini,Roberto Mazzuoli,Vanina Lopez-Azarevich,Ricardo Sureda,Miguel Azarevich,Valerio Acocella,Joel Ruch.LITHOS . 2014
[14]  
A tin-mineralized topaz rhyolite dike with coeval topaz granite enclaves at Qiguling in the Qitianling tin district, southern China[J] . Lei Xie,Rucheng Wang,Jun Chen,Jinchu Zhu,Wenlan Zhang,Jianjun Lu,Rongqing Zhang.LITHOS . 2013
[15]   The missing link between granites and granitic pegmatites [J].
Thomas, Rainer ;
Davidson, Paul .
JOURNAL OF GEOSCIENCES, 2013, 58 (02) :183-200
[16]  
Volcanoplutonic association of felsic rocks in the rare-metal ore units of Transbaikalia: Geochemistry of rocks and melts, age, and P - T conditions of their crystallization[J] . L. F. Syritso,E. V. Badanina,V. S. Abushkevich,E. V. Volkova,E. V. Shuklina.Petrology . 2012 (6)
[17]  
Geochemistry of the Late Neoproterozoic Hadb adh Dayheen ring complex, Central Arabian Shield: Implications for the origin of rare-metal-bearing post-orogenic A-type granites[J] . A.M. Moghazi,H.M. Harbi,K.A. Ali.Journal of Asian Earth Sciences . 2011 (6)
[18]  
The role of H2O in rapid emplacement and crystallization of granite pegmatites: resolving the paradox of large crystals in highly undercooled melts[J] . Nabelek,Peter I,Whittington,Alan G,Sirbescu,Mona-liza C.Contributions to Mineralogy and Petrology . 2010 (3)
[19]  
The role of fluorine in the concentration and transport of lithophile trace elements in felsic magmas: Insights from the Gawler Range Volcanics, South Australia[J] . Andrea Agangi,Vadim S. Kamenetsky,Jocelyn McPhie.Chemical Geology . 2010 (3)
[20]  
Geochemistry and formation conditions of rare-metal granites with various fluorine-bearing minerals (fluorite, topaz, and cryolite)[J] . V. S. Antipin,E. A. Savina,M. A. Mitichkin.Geochemistry International . 2006 (10)