石墨烯模板法制备类似三明治结构的多孔碳纳米片用于高效催化酸/碱性条件下氧还原反应的研究(英文)

被引：9

作者：

汪韬 ^{[1
]}

王健宇 ^{[2
]}

王绪 ^{[1
]}

杨佳 ^{[1
]}

刘建国 ^{[2
]}

徐航勋 ^{[1
]}

机构：

[1] CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China

[2] National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Collaborative Innovation Center of Advanced Microstructures, Nanjing

来源：

ScienceChinaMaterials | 2018年 / 61卷 / 07期

关键词：

oxygen reduction reaction; porous carbon; nanosheets; fuel cells; zinc-air batteries;

D O I：

暂无

中图分类号：

TM911.4 [燃料电池];

学科分类号：

摘要：

开发低成本,高性能氧还原反应（ORR）电催化剂对于燃料电池和金属空气电池的规模化应用至关重要.基于石墨烯的碳催化剂已经被广泛用于碱性电解质中的ORR.然而,与Pt/C催化剂相比,石墨烯基催化剂在酸性电解质中的性能仍然需要进一步提升.在这个工作中,我们发展了一种非常高效的模板方法来制备基于石墨烯的具有三明治结构的多孔碳纳米片电催化剂,其在碱性和酸性电解质中均具有非常好的ORR催化性能.首先,被氧化石墨烯吸附的苯二胺分子通过氧化聚合形成富氮聚合物网络,接着铁（Fe）盐被吸附到聚合物网络中,并且在热解之后形成ORR活性位点Fe–N–C以及Fe,Fe S和Fe N0.05纳米颗粒,最终得到类似三明治结构的碳纳米片ORR电催化剂.由于这种结构中存在较高密度的ORR活性位点,所获得的催化剂显示出非常高效的ORR活性,在0.1 mol L-1KOH中半波电位比Pt/C高30 m V.更重要的是,在0.1 mol L-1HCl O4中,催化剂的半波电位仅比Pt/C低约40 m V.这种独特的平面三明治结构可以在催化反应中暴露出丰富的ORR活性位点,同时,石墨烯层和多孔结构可以提高电导率以及促进传质,这两者对于实现高活性ORR催化至关重要.在碱性和酸性条件中,突出的电催化活性和耐久性表明这些碳纳米片作为贵金属基ORR催化剂的替代物具有很大的潜力,优秀的锌空气电池和质子交换膜燃料电池性能直接证实这种材料在实际电化学能源转化装置中也非常有应用前景.

引用

页码：915 / 925

页数：11

共 27 条

[11] Metal–Organic Framework‐Derived Bamboo‐like Nitrogen‐Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen‐Reduction Electrocatalysts[J] . Qing Li,Hengyu Pan,Drew Higgins,Ruiguo Cao,Guoqi Zhang,Haifeng Lv,Kangbing Wu,Jaephil Cho,Gang Wu.Small . 2015 (12)
[12] ZIF‐8 Derived Graphene‐Based Nitrogen‐Doped Porous Carbon Sheets as Highly Efficient and Durable Oxygen Reduction Electrocatalysts＜link href="#nss"/＞[J] . Hai‐xia Zhong,Jun Wang,Yu‐wei Zhang,Wei‐lin Xu,Wei Xing,Dan Xu,Yue‐fei Zhang,Xin‐bo Zhang.Angew. Chem. Int. Ed. . 2014 (51)
[13] A carbon-nanotube-supported graphene-rich non-preciousmetal oxygen reduction catalyst with enhanced performance durability. Wu G,More K L,Xu P, et al. ChemicalCommunications . 2013
[14] Identification of the nitrogen species on N-doped graphene layers and Pt / NG composite catalyst for direct methanol fuel cell. Le-Sheng Zhang,Xian-Qing Liang,Wei-Guo Song,Zi-Yu Wu. Physical Chemistry Chemical Physics . 2010
[15] ZIF-derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction. Zhang, P,Sun, F,Xiang, Z,Shen, Z,Yun, J,Cao, D. Energy Environ. Sci . 2014
[16] Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts. Yin, P. Q,Yao, T,Wu, Y,Zheng, L. R,Lin, Y,Liu, W,Ju, H. X,Zhu, J. F,Hong, X,Deng, Z. X,Zhou, G,Wei, S. Q,Li, Y. D. Angew Chem.Int.Ed . 2016
[17] Reactive multifunctional template-induced preparation of Fe-N-doped mesoporous carbon microspheres towards highly efficient electrocatalysts for oxygen reduction. Meng F L,Wang Z L,Zhong H X,et al. Advanced Materials . 2016
[18] Metal–Nitrogen Doping of Mesoporous Carbon/Graphene Nanosheets by Self‐Templating for Oxygen Reduction Electrocatalysts[J] . Shuang Li,Dongqing Wu,Haiwei Liang,Jinzuan Wang,Xiaodong Zhuang,Yiyong Mai,Yuezeng Su,Xinliang Feng.ChemSusChem . 2014 (11)
[19] Unravelling the Structure of Electrocatalytically Active Fe–N Complexes in Carbon for the Oxygen Reduction Reaction＜link href="#nss"/＞[J] . Yansong Zhu,Bingsen Zhang,Xin Liu,Da‐Wei Wang,Dang Sheng Su.Angew. Chem. Int. Ed. . 2014 (40)
[20] Facile One‐Pot, One‐Step Synthesis of a Carbon Nanoarchitecture for an Advanced Multifunctonal Electrocatalyst[J] . Zhenhai Wen,Suqin Ci,Yang Hou,Junhong Chen.Angew. Chem. . 2014 (25)

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