Radical chemistry of tert-butyl hydroperoxide (TBHP).: Part 1.: Studies of the FeIII-TBHP mechanism

被引：59

作者：

Barton, DHR ^{[1
]}

Le Gloahec, VN

Patin, H

Launay, F

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Ecole Natl Super Chim Rennes, F-35700 Rennes, France

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 06期

关键词：

D O I：

10.1039/a709266k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By maintaining the iron catalyst in the feme state, the oxidation of 2,4,6-tri-tert-butylphenol with TBHP affords exclusively tert-butyl-peroxylated products. Mechanistic interpretation does not require a higher valence state of iron than Fe-III.

引用

页码：559 / 563

页数：5

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