Multifunctional coordination compounds: design and properties

被引：21

作者：

Decurtins, S ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1999年 / 357卷 / 1762期

关键词：

coordination compounds; network compounds; oxalate complexes; molecular magnetism; energy transfer;

D O I：

10.1098/rsta.1999.0479

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Cleverly designed molecular building blocks provide chemists with the tools of a powerful molecular-scale construction set. They enable them to engineer materials that have a predictable order and useful solid-state properties. Hence, it is in the realm of supramolecular chemistry to follow a strategy for synthesizing materials that combine a selected set of properties, for instance from the areas of magnetism, photophysics and electronics. As a possible approach, host-guest solids that are based on extended anionic, homo- and bi-metallic oxalato-bridged transition-metal compounds with two- and three-dimensional connectivities are investigated. In particular, we report in detail about their structural properties and their multifunctional characteristics in the area of molecular magnetism and photophysics.

引用

页码：3025 / 3040

页数：16

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