Microtubes of conducting polymers

被引：56

作者：

Wan, MX ^{[1
]}

Huang, J ^{[1
]}

Shell, YQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Organ Solid Lab, Inst Chem, Beijing 100080, Peoples R China

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

polypyrrole; polyaniline; scanning transmission electron microscopy;

D O I：

10.1016/S0379-6779(98)00302-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new simple method termed as in-situ doping polymerization at presence of special organic sulfonic acids as dopants was proposed to synthesize conducting microtubes of polypyrrole (PPy) and polyaniline (PANI). The resulting microtubes not only show high conductivity at room temperature (e.g 27 S/cm for PPy and 4 S/cm for PANI), but also are soluble hi some organic solvents. Compared to "template synthesis(j)+/- method, which is an effective method to synthesize microtubes of conducting polymers, the new method proposed by authors is much simpler without using template membrane and "molecular anchor", which are required for "template synthesis" method.

引用

页码：708 / 711

页数：4

共 24 条

[11]

LIANG W, 1991, J AM CHEM SOC, V112, P9666

[12] ELECTROCHEMICAL CHARACTERISTICS OF POLYANILINE CATHODES AND ANODES IN AQUEOUS-ELECTROLYTES [J].

MACDIARMID, AG ;

MU, SL ;

SOMASIRI, NLD ;

WU, WQ .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4) :187-190

[13] TEMPLATE SYNTHESIS OF ORGANIC MICROTUBULES [J].

MARTIN, CR ;

VANDYKE, LS ;

CAI, ZH ;

LIANG, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) :8976-8977

[14] TEMPLATE SYNTHESIS OF ELECTRONICALLY CONDUCTIVE POLYMERS - A NEW ROUTE FOR ACHIEVING HIGHER ELECTRONIC CONDUCTIVITIES [J].

MARTIN, CR ;

PARTHASARATHY, R ;

MENON, V .

SYNTHETIC METALS, 1993, 55 (2-3) :1165-1170

[15]

MOON YB, 1989, POLYM COMMUN, V30, P196

[16]

MOTT NF, 1979, ELECT PROCESSES NONC, pP34

[17] POLYANILINE TREATED WITH ORGANIC-ACIDS - DOPING CHARACTERISTICS AND STABILITY [J].

NEOH, KG ;

PUN, MY ;

KANG, ET ;

TAN, KL .

SYNTHETIC METALS, 1995, 73 (03) :209-215

[18]

POOL R, 1990, SCIENCE, V247, P1410

[19]

Reginald MP, 1986, J ELECTROCHEM SOC, V133, P2206

[20]

SHIRAKAWA H, 1978, MAKROMOL CHEM, V179, P1565

← 1 2 3 →