Preparation and structural characterisation of bis(4′-(3-pyridyl)-2,2′:6′,2"-terpyridine)ruthenium(II) hexafluorophosphate

被引：26

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Neuburger, M ^{[1
]}

Schaffner, S ^{[1
]}

Schaper, F ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 04期

关键词：

rutheniun-(II); X-ray; 2,2 ': 6 ',2 ''-terpyridine; synthesis;

D O I：

10.1016/j.inoche.2006.02.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient synthesis of the ligand 4'-(3-pyridyl)-2,2':6',2"-terpyridine (2) is presented and the preparation, spectroscopic and structural characterisation of the metallotecton [Ru(2)(2)](2+) are reported. (c) 2006 Elsevier B.V. All rights reserved.

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页码：433 / 436

页数：4

相关论文

共 11 条

[1] Efficient synthesis of pyridines via a sequential solventless aldol condensation and Michael addition [J].

Cave, GWV ;

Raston, CL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (24) :3258-3264

[2] Toward benign syntheses of pyridines involving sequential solvent free aldol and Michael addition reactions [J].

Cave, GWV ;

Raston, CL .

CHEMICAL COMMUNICATIONS, 2000, (22) :2199-2200

[3] PENDANT-FUNCTIONALIZED LIGANDS FOR METALLOSUPRAMOLECULAR ASSEMBLIES - RUTHENIUM(II) AND OSMIUM(II) COMPLEXES OF 4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (09) :1409-1418

[4] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[5] Metal-directed assembly of a box-like structure [J].

Constable, EC ;

Schofield, E .

CHEMICAL COMMUNICATIONS, 1998, (03) :403-404

[6] Development of supramolecular structure through alkylation of pendant pyridyl functionality [J].

Constable, EC ;

Housecroft, CE ;

Neuburger, M ;

Phillips, D ;

Raithby, PR ;

Schofield, E ;

Sparr, E ;

Tocher, DA ;

Zehnder, M ;

Zimmermann, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (13) :2219-2228

[7] LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (20) :2947-2950

[8]

CONSTABLE EC, 2006, IN PRESS CHEM EUR J

[9] Iridium(III) bis-terpyridine complexes incorporating pendent N-methylpyridinium groups:: luminescent sensors for chloride ions [J].

Goodall, W ;

Williams, JAG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (17) :2893-2895

[10] New self-assembled structural motifs in coordination chemistry [J].

Swiegers, Gerhard F. ;

Malefetse, Tshepo J. .

Chemical Reviews, 2000, 100 (09) :3483-3537