Tetrabutylammonium Decatungstate (Chemo)selective Photocatalyzed, Radical C-H Functionalization in Amides

被引：66

作者：

Angioni, Simone ^{[1
]}

Ravelli, Davide ^{[1
]}

Emma, Daniele ^{[1
,2
]}

Dondi, Daniele

Fagnoni, Maurizio ^{[1
]}

Albini, Angelo ^{[1
]}

机构：

[1] Univ Pavia, Dept Organ Chem, I-27100 Pavia, Italy

[2] Univ Pavia, Dept Gen Chem, I-27100 Pavia, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 14-15期

关键词：

amides; conjugate alkylation; electron-poor olefins; photochemical reactions; radical reactions;

D O I：

10.1002/adsc.200800378

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Photoamidation of electron-poor olefins has been achieved by means of a radical-induced C-H functionalization in amides. Tetrabutylammonium decatungstate was used as photocatalyst of the reaction and allowed the smooth generation of different carbon-centered radicals depending on the amide structure.

引用

收藏

页码：2209 / 2214

页数：6

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