Synthesis, characterisation and X-ray structure of an azido adduct of a tridentate (NNO) Schiff base nickel(II) complex

被引：7

作者：

Adhikary, Chandan

Mal, Dasarath

Chaudhuri, Siddhartha

Koner, Subratanath ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Jadavpur 700032, Kolkata, India

[2] Bose Inst, SAIF, Kolkata 700009, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 59卷 / 07期

关键词：

nickel(II); azide; tridentate Schiff base; synthesis; crystal structure;

D O I：

10.1080/00958970500266024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tridentate Schiff base 1-(N-salicylideneimino)-2-(N,N-diethyl-aminoethane (HL), derived from the condensation of salicylaldehyde with N,N-diethylethylenediamine, reacted with nickel(II) nitrate and azide to give a mononuclear complex of formula [Ni(L)(N-3)], where HL = Et2N(CH2)(2)NCHC6H4(OH). The complex was characterized by spectroscopic and X-ray crystallographic methods. Coordination around nickel(II) is square planar. The molecular and supramolecular structure of the complex is discussed.

引用

收藏

页码：699 / 704

页数：6

相关论文

共 28 条

[1] DETERMINATION OF SUPEROXIDE DISMUTASE-LIKE ACTIVITY IN SOME DIVALENT METAL SACCHARINATES [J].

APELLA, MC ;

TOTARO, R ;

BARAN, EJ .

BIOLOGICAL TRACE ELEMENT RESEARCH, 1993, 37 (2-3) :293-299

[2] A MODEL FOR VITAMIN-B6-AMINO-ACID-RELATED METAL-COMPLEXES - NEUTRON-DIFFRACTION STUDY OF AQUA(N-SALICYLIDENEGLYCINATO)COPPER(II) HEMIHYDRATE AT 130-K [J].

BKOUCHEWAKSMAN, I ;

BARBE, JM ;

KVICK, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1988, 44 :595-601

[3]

Blahova M, 1993, Cesk Farm, V42, P137

[4] Crystal structures and superoxide dismutase mimetic activity of [CuL(2)(Him)(2)]center dot MeOH and [CuL(2)(mim)(2)]center dot H2O [HL=4-amino-N-(thiazol-2-yl)benzenesulfonamide, Him equals imidazole, mim equals N-methylimidazole] [J].

Casanova, J ;

Alzuet, G ;

Borras, J ;

Carugo, O .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (11) :2239-2244

[5] First report of singly phenoxo-bridged copper(II) dimeric complexes: synthesis, crystal structure and low-temperature magnetic behaviour study [J].

Choudhury, CR ;

Dey, SK ;

Karmakar, R ;

Wu, CD ;

Lu, CZ ;

El Fallah, MS ;

Mitra, S .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (09) :1360-1366

[6] NEW ROUTE TO BIMETALLIC IMIDAZOLATE-BRIDGED COMPLEXES .6. STRUCTURAL AND MAGNETIC CONSEQUENCES OF STERIC EFFECTS IN MONONUCLEAR AND DINUCLEAR NICKEL(II) AND COPPER(II) COMPLEXES INVOLVING 4-METHYLIMIDAZOLE AS LIGAND [J].

COSTES, JP ;

DAHAN, F ;

LAURENT, JP .

INORGANIC CHEMISTRY, 1991, 30 (08) :1887-1892

[7]

CROMER DT, 1994, INT TABLES XRAY CRYS, V4

[8] Crystal structure and magnetic interactions in nickel(II) dibridged complexes formed by two azide groups or by both phenolate oxygen-azide, -thiocyanate, -carboxylate, or -cyanate groups [J].

Dey, SK ;

Mondal, N ;

El Fallah, MS ;

Vicente, R ;

Escuer, A ;

Solans, X ;

Font-Bardía, M ;

Matsushita, T ;

Gramlich, V ;

Mitra, S .

INORGANIC CHEMISTRY, 2004, 43 (07) :2427-2434

[9] MECHANISM OF NON-ENZYMIC TRANSAMINATION REACTION BETWEEN HISTIDINE AND ALPHA-OXOGLUTARIC ACID [J].

DOCTOR, VM ;

ORO, J .

BIOCHEMICAL JOURNAL, 1969, 112 (05) :691-&

[10] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)