New phosphate fluorosurfactants for carbon dioxide

被引：75

作者：

Keiper, JS

Simhan, R

DeSimone, JM

Wignall, GD

Melnichenko, YB

Frielinghaus, H

机构：

[1] Univ N Carolina, Dept Chem, NSF Ctr Environmentally Responsible Solvents & Pr, Chapel Hill, NC 27599 USA

[2] N Carolina State Univ, Dept Chem Engn, Raleigh, NC 27695 USA

[3] Oak Ridge Natl Lab, Div Solid State, Oak Ridge, TN 37831 USA

[4] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 09期

关键词：

D O I：

10.1021/ja0122142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anionic phosphate fluorosurfactants were shown to self-assemble into water-in-carbon dioxide microemulsions. The surfactants, having either two fluorinated chains or one fluorinated chain and one hydrocarbon chain, facilitated significant water uptake in CO2. Small angle neutron scattering (SANS) measurements of surfactant/water/CO2 solutions confirmed the presence of nanometer-scale aggregates, indicative of microemulsion formation. Copyright © 2002 American Chemical Society.

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页码：1834 / 1835

页数：2

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