Droplet structure in a water-in-CO2 microemulsion

被引:111
作者
Eastoe, J
Bayazit, Z
Martel, S
Steytler, DC
Heenan, RK
机构
[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND
[2] RUTHERFORD APPLETON LAB,CLRC,ISIS,CHILTON OX11 0QX,OXON,ENGLAND
关键词
D O I
10.1021/la950546c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-pressure small-angle neutron-scattering measurements show that a dichain hydrocarbon-fluorocarbon surfactant ((C7H15)(C7F15)CHSO4-Na+) stabilizes spherical droplets, with mean water core radius around 25 Angstrom, in a water-in-CO2 microemulsion (temperature = 25 degrees C, pressure = 500 bar). At lower pressures droplet clustering is observed. Our structural work on this system builds on initial phase stability studies by Johnston et al.
引用
收藏
页码:1423 / 1424
页数:2
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