Coordination modulation induced and ultrasonic-assisted synthesis of size-controlled microporous metal-imidazolate framework crystals with enhanced adsorption performance

被引：23

作者：

Liu, Qing ^{[1
]}

Jin, Li-Na ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing Natl Lab Microstruct,Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 41期

基金：

中国国家自然科学基金;

关键词：

ORGANIC FRAMEWORKS; POLYMER;

D O I：

10.1039/c3ce41133h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Size-controlled metal-imidazolate framework crystals have been synthesized by combining the coordination modulation method and ultrasonic-assisted synthesis for the first time. Aqueous ammonia was used as the coordination modulator, and was found to be able to control the crystal size. The as-obtained crystals had improved adsorption properties compared with that of the bulk ones.

引用

收藏

页码：8250 / 8254

页数：5

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