Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L=1,4-di(1H-imidazol-4-yl)benzene]

被引：174

作者：

Chen, Shui-Sheng ^{[1
,3
]}

Chen, Min ^{[1
]}

Takamizawa, Satoshi ^{[2
]}

Chen, Man-Sheng ^{[1
]}

Su, Zhi ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China

[2] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, Kanagawa 2360027, Japan

[3] Fuyang Teachers Coll, Sch Chem & Chem Engn, Fuyang 236041, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 02期

基金：

中国国家自然科学基金;

关键词：

ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CARBON-DIOXIDE; TRIAZOLATE FRAMEWORKS; ADSORPTION PROPERTIES; ZEOLITIC TOPOLOGIES; CRYSTAL-STRUCTURE; BINDING; METHANE; CO2;

D O I：

10.1039/c0cc04085a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H2L) and CuCl2 center dot 2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L2-, and shows temperature dependent selective gas sorption properties.

引用

页码：752 / 754

页数：3

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