The red form of [Re(phen)(CO)3(H2O)]-CF3SO3•H2O

被引：12

作者：

Connick, WB ^{[1
]}

Di Bilio, AJ ^{[1
]}

Schaefer, WP ^{[1
]}

Gray, HB ^{[1
]}

机构：

[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199001432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C12H8N2)(CO)(3)-(H2O)]CF3SO3. H2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar pi-stacked structure.

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页码：913 / 916

页数：4

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