Spatially confined corner defects induce chemical functionality of TiO2 nanorods

被引：47

作者：

Rabatic, BM

Dimitrijevic, NM

Cook, RE

Saponjic, ZV

Rajh, T ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Chem, Ctr Nanoscale Mat, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Sci Mat, Argonne, IL 60439 USA

来源：

ADVANCED MATERIALS | 2006年 / 18卷 / 08期

关键词：

D O I：

10.1002/adma.200500988

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The atomic structure of anisotropic titanium dioxide nanoparticles is characterized by HRTEM to identify coordination defects at the tip surfaces of the nanorods (see figure). At the tip regions of the nanoparticles, the titanium metal-metal atom spacings extend between the (001.) planes and demonstrate site-specific chemical reactivity towards surface modifiers. The observed reactivity of the nanorod tip is reminiscent of selectivity found in organic and biological self-organizing systems.

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页码：1033 / +

页数：6

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