Hydration numbers of glycine in aqueous sodium chloride and urea solutions

被引：3

作者：

Korolev, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 02期

关键词：

sodium chloride; urea; glycine; aqueous solutions; partial volumes; hydration numbers; APPARENT MOLAR VOLUMES; AMINO-ACIDS; HEAT-CAPACITIES; ISENTROPIC COMPRESSIBILITIES; ALKALI-HALIDES; WATER; ELECTROLYTES; ALANINE; TETRAALKYLAMMONIUM; ENTHALPIES;

D O I：

10.1134/S0022476613020248

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

The hydration number of the glycine amino acid in aqueous sodium chloride solution is less than in aqueous urea solution; the difference increases significantly with increasing concentration of the nonaqueous component. Given the same partial volume of water, the hydration numbers of glycine in the two systems are close together (delta a parts per thousand 5%).

引用

页码：446 / 450

页数：5

共 38 条

[1]

ULTRASONIC STUDY OF DILUTE AQUEOUS SOLUTIONS OF UREA, GUANIDINE HYDROCHLORIDE AND DIOXANE [J].

ARAKAWA, K ;

TAKENAKA, N ;

SASAKI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (03) :636-+

[2]

THERMODYNAMIC ULTRASONIC SPECTROSCOPIC AND MISCIBILITY STUDIES OF WATER+METHYL CYANIDE SOLUTIONS [J].

ARMITAGE, DA ;

BLANDAMER, MJ ;

FOSTER, MJ ;

HIDDEN, NJ ;

MORCOM, KW ;

SYMONS, MCR ;

WOOTTEN, MJ .

TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (545P) :1193-+

[3]

OPPOSITE EFFECT OF UREA AND SOME OF ITS DERIVATIVES ON WATER STRUCTURE [J].

BARONE, G ;

RIZZO, E ;

VITAGLIA.V .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (10) :2230-&

[4]

Impact of protein denaturants and stabilizers on water structure [J].

Batchelor, JD ;

Olteanu, A ;

Tripathy, A ;

Pielak, GJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (07) :1958-1961

[5]

PARTIAL MOLAR HEAT-CAPACITIES AND VOLUMES OF TRANSFER OF SOME AMINO-ACIDS AND PEPTIDES FROM WATER TO AQUEOUS SODIUM-CHLORIDE SOLUTIONS AT 298.15-K [J].

BHAT, R ;

AHLUWALIA, JC .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (07) :1099-1105

[6]

ENTHALPIES OF DILUTION OF AQUEOUS-SOLUTIONS CONTAINING STRUCTURE-BREAKING SOLUTES AND POLYOLS - BIURET POLYOL WATER AND THIOUREA POLYOL WATER-SYSTEMS AT 29816K [J].

CASCELLA, C ;

CASTRONUOVO, G ;

ELIA, V ;

SARTORIO, R ;

WURZBURGER, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :3289-3299

[7]

Structure of concentrated aqueous NaCl solution:: A Monte Carlo study [J].

Degrève, L ;

da Silva, FLB .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (06) :3070-3078

[8]

APPARENT MOLAL HEAT-CAPACITIES AND VOLUMES OF AMINO-ACIDS IN AQUEOUS POLYOL SOLUTIONS [J].

DIPAOLA, G ;

BELLEAU, B .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (13) :1827-1831

[9]

Thermodynamic Properties of Alkali Halides. II. Enthalpies of Dilution and Heat Capacities in Water at 25 degrees C [J].

Fortier, J. -L. ;

Leduc, P. -A. ;

Desnoyers, J. E. .

JOURNAL OF SOLUTION CHEMISTRY, 1974, 3 (04) :323-349

[10]

STRUCTURAL APPROACH TO SOLVENT POWER OF WATER FOR HYDROCARBONS - UREA AS A STRUCTURE BREAKER [J].

FRANK, HS ;

FRANKS, F .

JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (10) :4746-&

← 1 2 3 4 →