Pt Nanoparticle-Dispersed Graphene-Wrapped MWNT Composites As Oxygen Reduction Reaction Electrocatalyst in Proton Exchange Membrane Fuel Cell

被引:49
作者
Aravind, S. S. Jyothirmayee [1 ]
Ramaprabhu, Sundara [1 ]
机构
[1] Indian Inst Technol, Dept Phys, Alternat Energy & Nanotechnol Lab AENL, Nanofunct Mat Technol Ctr NFMTC, Madras 600036, Tamil Nadu, India
关键词
graphene; carbon nanotube; Pt nanoparticles; chemical vapor deposition; fuel cells; power density; CARBON NANOTUBE; PLATINUM;
D O I
10.1021/am301187h
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Chemical and electrical synergies between graphite oxide and multiwalled carbon nanotube (MWNT) for processing graphene wrapped-MWNT hybrids has been realized by chemical vapor deposition without any chemical functionalization. Potential of the hybrid composites have been demonstrated by employing them as electrocatalyst supports in proton exchange membrane fuel cells. The defects present in the polyelectrolyte, which have been c wrapped over highly dispersed MWNT, act as anchoring sites for the homogeneous deposition of platinum nanoparticles. Single cell proton exchange membrane fuel cells show that the power density of the hybrid composite based fuel cells is higher compared to the pure catalyst-support-based fuel cells, because of enhanced electrochemical reactivity and good surface area of the nanocomposites.
引用
收藏
页码:3805 / 3810
页数:6
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