Structural distortions in Pd-MeO-Biphep and Pd-Binap aryl complexes.: Anomalies induced via electronic effects

被引：21

作者：

Drago, D

Pregosin, PS ^{[1
]}

Tschoerner, M

Albinati, A

机构：

[1] ETH Zentrum, Inorgan Chem Lab, CH-8092 Zurich, Switzerland

[2] Univ Milan, Chem Pharm, I-20131 Milan, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a903509e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The four-coordinate complexes [PdBr(p-NCC6H4)(MeO-Biphep)], 1 [MeO-Biphep = 6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl], and [PdBr(p-NCC6H4)(p-tol-Binap)], 2 [p-tol-Binap = 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl], both distort markedly, with the former no longer square-planar, and the latter, possessing the longest recorded Pd-P bond length.

引用

页码：2279 / 2280

页数：2

共 30 条

[1] EVIDENCE FOR THE LIGATION OF PALLADIUM(0) COMPLEXES BY ACETATE IONS - CONSEQUENCES ON THE MECHANISM OF THEIR OXIDATIVE ADDITION WITH PHENYL IODIDE AND PHPD(OAC)(PPH(3))(2) AS INTERMEDIATE IN THE HECK REACTION [J].