An NMR investigation of the merocyanine dyes generated by protolysis of some novel spironaphthopyranoindoles

被引:25
作者
Gabbutt, CD [1 ]
Hepworth, JD [1 ]
Heron, BM [1 ]
机构
[1] Univ Hull, Dept Chem, Hull HU6 7RX, N Humberside, England
关键词
photochromism; merocyanine dyes; nmr spectroscopy; synthesis; spiroindolinonaphthopyran (NIPS); protolysis;
D O I
10.1016/S0143-7208(99)00007-8
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Two novel amino-substituted spiroindolinonaphthopyrans have been synthesised. Whilst these compounds exhibit no observable photochromic properties at ambient temperature, protonation gives stable, intensely coloured dyes. H-1 nmr spectroscopy has been used to establish the configuration of these dyes. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:35 / 43
页数:9
相关论文
共 56 条
[51]   THE PH CONTROL OF THE DECOLORATION RATE OF SPIRONAPHTHOXAZINE DERIVATIVES [J].
YAMAGUCHI, T ;
TAMAKI, T ;
KAWANISHI, Y ;
SEKI, T ;
SAKURAGI, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (12) :867-869
[52]   NEGATIVE PHOTOCHROMISM OF 3,1'-TRIMETHYLENE-BRIDGED 6-NITROINDOLINOSPIROPYRAN [J].
YOKOYAMA, Y ;
SHIROYAMA, T .
CHEMISTRY LETTERS, 1995, (01) :71-72
[53]   DETAILED INVESTIGATION ON A NEGATIVE PHOTOCHROMIC SPIROPYRAN [J].
ZHOU, JW ;
LI, YT ;
TANG, YW ;
ZHAO, FQ ;
SONG, XQ ;
LI, EC .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1995, 90 (2-3) :117-123
[54]  
1989, Patent No. 316179
[55]  
1998, Patent No. 28235
[56]  
1990, Patent No. 4913544