Controlling wettability and photochromism in a dual-responsive tungsten oxide film

被引:207
作者
Wang, ST
Feng, XJ
Yao, JN
Jiang, L [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
关键词
nanostructures; photochromism; surface chemistry; tungsten; wettability;
D O I
10.1002/anie.200502061
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A wet and dry paper! Tungsten oxide films prepared by a facile electrochemical deposition process provide the first example of a dual surface functionality. The reversible switch of wettability between superhydrophobicity and superhydrophilicity is realized by alternating irradiation with UV light and storage in the dark; this phenomenon is accompanied by photochromism (see picture). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1264 / 1267
页数:4
相关论文
共 52 条
[31]   ELECTROCHROMISM OF WO3 LIALF4 LILN THIN-FILM OVERLAYERS [J].
OI, T ;
MIYAUCHI, K ;
UEHARA, K .
JOURNAL OF APPLIED PHYSICS, 1982, 53 (03) :1823-1823
[32]   Super-water-repellent fractal surfaces [J].
Onda, T ;
Shibuichi, S ;
Satoh, N ;
Tsujii, K .
LANGMUIR, 1996, 12 (09) :2125-2127
[33]   Photon-modulated wettability changes on spiropyran-coated surfaces [J].
Rosario, R ;
Gust, D ;
Hayes, M ;
Jahnke, F ;
Springer, J ;
Garcia, AA .
LANGMUIR, 2002, 18 (21) :8062-8069
[34]   Surface-responsive materials [J].
Russell, TP .
SCIENCE, 2002, 297 (5583) :964-967
[35]   THE PERFORMANCE OF ELECTROCHROMIC TUNGSTEN TRIOXIDE FILMS DOPED WITH COBALT OR NICKEL [J].
SHEN, PK ;
SYEDBOKHARI, J ;
TSEUNG, ACC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (09) :2778-2783
[36]   All-solid-state electrochromic window of prussian blue and electrodeposited WO3 film with poly(ethylene oxide) gel electrolyte [J].
Su, LY ;
Wang, H ;
Lu, ZH .
MATERIALS CHEMISTRY AND PHYSICS, 1998, 56 (03) :266-270
[37]   Nanocrystalline tungsten oxide thin film: Preparation, microstructure, and photochromic behavior [J].
Sun, M ;
Xu, N ;
Cao, YW ;
Yao, JN ;
Wang, EG .
JOURNAL OF MATERIALS RESEARCH, 2000, 15 (04) :927-933
[38]   Photoinduced surface wettability conversion of ZnO and TiO2 thin films [J].
Sun, RD ;
Nakajima, A ;
Fujishima, A ;
Watanabe, T ;
Hashimoto, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (10) :1984-1990
[39]   Reversible switching between superhydrophilicity and superhydrophobicity [J].
Sun, TL ;
Wang, GJ ;
Feng, L ;
Liu, BQ ;
Ma, YM ;
Jiang, L ;
Zhu, DB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (03) :357-360
[40]  
Turyan I, 2000, ADV MATER, V12, P330, DOI 10.1002/(SICI)1521-4095(200003)12:5<330::AID-ADMA330>3.0.CO