Methods for the synthesis of the Diels-Alder catalysts (ArO)2TiX2 (X = Cl, Br, I; Ar=2-tert-butyl-6-methylphenyl)

被引：26

作者：

Santora, BP ^{[1
]}

White, PS ^{[1
]}

Gagné, MR ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem CB 3290, Chapel Hill, NC 27599 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 13期

关键词：

D O I：

10.1021/om9808099

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A procedure for converting titanium diethylamidos to the corresponding dihalides (Cl, Br, I) and a complementary method for converting titanium dichlorides into dibromides and diiodides are reported These methods were utilized to synthesize a family of homogeneous and polymer-supported Diels-Alder catalysts with the general formula (ArO)(2)TiX2 (X = Cl, Br, I; Ar =2-tert-butyl-6-methylphenyl).

引用

页码：2557 / 2560

页数：4

共 16 条

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