Inertial effects in anomalous dielectric relaxation

被引:26
作者
Coffey, WT [1 ]
Kalmykov, YP
Titov, SV
机构
[1] Univ Dublin Trinity Coll, Sch Engn, Dept Elect Engn & Elect, Dublin 2, Ireland
[2] Univ Perpignan, Ctr Etud Fondamentales, F-66860 Perpignan, France
[3] Russian Acad Sci, Inst Radioengn & Elect, Fryazino 114190, Moscow Region, Russia
来源
PHYSICAL REVIEW E | 2002年 / 65卷 / 03期
基金
俄罗斯基础研究基金会;
关键词
Brownian movement - Correlation methods - Diffusion - Energy absorption - Functions - Mathematical models - Transparency;
D O I
10.1103/PhysRevE.65.032102
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The inertia corrected Debye model of rotational Brownian motion of polar molecules is generalized to fractional dynamics (anomalous diffusion) in the context of the fractional Klein-Kramers equation. The fractal generalization of the Gross-Sack solution for the complex dielectric susceptibility chi(omega) for an assembly of fixed axis rotators is given. The high-frequency behavior of chi(omega) is controlled by the inertia of a dipole as in normal diffusion, so that the Gordon sum rule for dipolar absorption is satisfied ensuring a return to optical transparency at very high frequencies.
引用
收藏
页码:1 / 032102
页数:4
相关论文
共 20 条
[1]   Fractional Kramers equation [J].
Barkai, E ;
Silbey, RJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (16) :3866-3874
[2]  
Coffey W., 1996, LANGEVIN EQUATION
[3]   Dipole-dipole interaction and anisotropy effects in the itinerant oscillator model [J].
Coffey, WT .
JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (13) :4960-4967
[4]   Crossover formulas in the Kramers theory of thermally activated escape rates - Application to spin systems [J].
Coffey, WT ;
Garanin, DA ;
McCarthy, DJ .
ADVANCES IN CHEMICAL PHYSICS, VOL. 117, 2001, 117 :483-765
[5]  
COFFEY WT, 1984, MOL DIFFUSION SPECTR
[6]  
EVANS MW, 1982, MOL DYNAMICS THEORY
[7]   FOX FUNCTION REPRESENTATION OF NON-DEBYE RELAXATION PROCESSES [J].
GLOCKLE, WG ;
NONNENMACHER, TF .
JOURNAL OF STATISTICAL PHYSICS, 1993, 71 (3-4) :741-757
[8]   INERTIAL EFFECTS AND DIELECTRIC RELAXATION [J].
GROSS, EP .
JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (08) :1415-1423
[9]   Matrix elements of the system of moment equations governing the kinetics of superparamagnetic particles [J].
Kalmykov, YP ;
Titov, SV .
PHYSICAL REVIEW LETTERS, 1999, 82 (14) :2967-2970
[10]  
MCCONNELL JR, 1980, ROTATIONAL BROWNIAN