Effect of La2O3 substitutions on structure and dielectric properties of Bi2O3-ZnO-Nb2O5-based pyrochlore ceramics

被引:29
作者
Wang, H [1 ]
Zhang, DS [1 ]
Wang, XL [1 ]
Yao, X [1 ]
机构
[1] Xian Jiao Tong Univ, Elect Mat Res Lab, Xian 710049, Peoples R China
关键词
Number:; -; Acronym:; XJTU; Sponsor: XiâÇÖan Jiaotong University;
D O I
10.1557/JMR.1999.0078
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of La2O3 substitutions on structure and dielectric properties of Bi2O3-ZnO-Nb2O5-based ceramics was investigated. Bi1.5-xLaxZn0.5(Zn0.5Nb1.5)O-7 samples were prepared by conventional ceramic processing technology. The crystal structure of the Bi1.5Zn0.5(Zn0.5Nb1.5)O-7 Sample was characterized as a pure cubic pyrochlore. With a lower amount of La2O3 substitution, the crystal structures were still cubic pyrochlore. Superlattice x-ray diffraction line was identified for some compositions. With the increasing amount of La2O3 substitution, the crystal structure gradually transformed from pure cubic pyrochlore to LaNbO4 phase. The dielectric properties regularly changed with the structure change. The structure-properties relations of the ceramics are discussed.
引用
收藏
页码:546 / 548
页数:3
相关论文
共 7 条
[1]   HIGH DIELECTRIC-CONSTANT AND SMALL TEMPERATURE-COEFFICIENT BISMUTH-BASED DIELECTRIC COMPOSITIONS [J].
LING, HC ;
YAN, MF ;
RHODES, WW .
JOURNAL OF MATERIALS RESEARCH, 1990, 5 (08) :1752-1762
[2]  
Mo Y. H., 1986, INORGANIC DIELECTRIC, P360
[3]  
Wang H, 1997, FERROELECTRICS, V195, P19, DOI 10.1080/00150199708260478
[4]  
Wang H., 1994, P 4 INT C EL CER APP, P143
[5]  
WANG H, 1996, P 10 IEEE INT S APPL, P787
[6]  
WANG X, 1994, Patent No. 1089247A
[7]   LOW-FIRING, TEMPERATURE-STABLE DIELECTRIC COMPOSITIONS BASED ON BISMUTH NICKEL ZINC NIOBATES [J].
YAN, MF ;
LING, HC ;
RHODES, WW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (04) :1106-1107