Polyamine-functionalized carbon quantum dots for chemical sensing

被引:586
作者
Dong, Yongqiang
Wang, Ruixue
Li, Hao
Shao, Jingwei
Chi, Yuwu [1 ]
Lin, Xiaomei
Chen, Guonan
机构
[1] Fuzhou Univ, MOE Key Lab Anal & Detect Technol Food Safety, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350108, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTROGENERATED CHEMILUMINESCENCE; NANOCRYSTALS;
D O I
10.1016/j.carbon.2012.02.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polyamine-functionalized carbon quantum dots (CQDs) with high fluorescence quantum yield (42.5%) have been synthesized by the low temperature (<200 degrees C) carbonization of citric acid with branched polyethylenimine (BPEI) in one simple step. The obtained BPEI-CQDs are spherical graphite nanocrystals (average 6.2 nm in size) capped with abundant BPEI at their surfaces. It is the first report that CQDs are both amino-functionalized and highly fluorescent, which suggests their promising applications in chemical sensing. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2810 / 2815
页数:6
相关论文
共 28 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Luminescent Carbon Nanodots: Emergent Nanolights [J].
Baker, Sheila N. ;
Baker, Gary A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6726-6744
[3]   Surface functionalized carbogenic quantum dots [J].
Bourlinos, Athanasios B. ;
Stassinopoulos, Andreas ;
Anglos, Demetrios ;
Zboril, Radek ;
Karakassides, Michael ;
Giannelis, Emmanuel P. .
SMALL, 2008, 4 (04) :455-458
[4]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[5]   Carbon dots for multiphoton bioimaging [J].
Cao, Li ;
Wang, Xin ;
Meziani, Mohammed J. ;
Lu, Fushen ;
Wang, Haifang ;
Luo, Pengju G. ;
Lin, Yi ;
Harruff, Barbara A. ;
Veca, L. Monica ;
Murray, Davoy ;
Xie, Su-Yuan ;
Sun, Ya-Ping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) :11318-+
[6]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[7]   Biophysical characterization of PEI/DNA complexes [J].
Choosakoonkriang, S ;
Lobo, BA ;
Koe, GS ;
Koe, JG ;
Middaugh, CR .
JOURNAL OF PHARMACEUTICAL SCIENCES, 2003, 92 (08) :1710-1722
[8]   Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots [J].
Ding, ZF ;
Quinn, BM ;
Haram, SK ;
Pell, LE ;
Korgel, BA ;
Bard, AJ .
SCIENCE, 2002, 296 (5571) :1293-1297
[9]   Extraction of Electrochemiluminescent Oxidized Carbon Quantum Dots from Activated Carbon [J].
Dong, Yongqiang ;
Zhou, Nana ;
Lin, Xiaomei ;
Lin, Jianpeng ;
Chi, Yuwu ;
Chen, Guonan .
CHEMISTRY OF MATERIALS, 2010, 22 (21) :5895-5899
[10]   In vivo cancer targeting and imaging with semiconductor quantum dots [J].
Gao, XH ;
Cui, YY ;
Levenson, RM ;
Chung, LWK ;
Nie, SM .
NATURE BIOTECHNOLOGY, 2004, 22 (08) :969-976