Isotopic effects may induce cooperativity in valence tautomeric transition

被引：28

作者：

Cador, O

Dei, A

Sangregorio, C

机构：

[1] Univ Florence, INSTM, UdR, I-50019 Florence, Italy

[2] Univ Florence, Dipartimento Chim, LAMM, I-50019 Florence, Italy

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 06期

关键词：

D O I：

10.1039/b313049e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The replacing of CH2Cl2 solvent molecules with their deuterated analogues in a Co complex undergoing valence-tautomeric interconversion drastically modifies its magnetic properties giving rise to a thermal hysteresis.

引用

页码：652 / 653

页数：2

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