Isotopic effects may induce cooperativity in valence tautomeric transition

被引：28

作者：

Cador, O

Dei, A

Sangregorio, C

机构：

[1] Univ Florence, INSTM, UdR, I-50019 Florence, Italy

[2] Univ Florence, Dipartimento Chim, LAMM, I-50019 Florence, Italy

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 06期

关键词：

D O I：

10.1039/b313049e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The replacing of CH2Cl2 solvent molecules with their deuterated analogues in a Co complex undergoing valence-tautomeric interconversion drastically modifies its magnetic properties giving rise to a thermal hysteresis.

引用

页码：652 / 653

页数：2

共 15 条

[11] THE CHEMISTRY OF TRANSITION-METAL COMPLEXES CONTAINING CATECHOL AND SEMIQUINONE LIGANDS [J].

PIERPONT, CG ;

LANGE, CW .

PROGRESS IN INORGANIC CHEMISTRY, VOL 41, 1994, 41 :331-442

[12] TRANSITION-METAL COMPLEXES OF ORTHO-BENZOQUINONE, ORTHO-SEMIQUINONE, AND CATECHOLATE LIGANDS [J].

PIERPONT, CG ;

BUCHANAN, RM .

COORDINATION CHEMISTRY REVIEWS, 1981, 38 (01) :45-87

[13] Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands [J].

Pierpont, CG .

COORDINATION CHEMISTRY REVIEWS, 2001, 216 :99-125

[14]

PRASSIDIS K, 1991, NATO ASI SER C, P343

[15] Density functional studies of a Heisenberg spin coupled chromium-semiquinone complex and its chromium-catechol analog [J].

Rodriguez, JH ;

Wheeler, DE ;

McCusker, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :12051-12068

← 1 2 →