White-light-emitting phosphor:: CaMgSi2O6:Eu2+, Mn2+ and its related properties with blending

被引:91
作者
Lee, Sung Hun
Park, Je Hong
Son, Se Mo
Kim, Jong Su [1 ]
Park, Hong Lee
机构
[1] Pukyong Natl Univ, Dept Image Syst Sci & Engn, Pusan 608739, South Korea
[2] Yonsei Univ, Inst Phys & Appl Phys, Seoul 120749, South Korea
关键词
D O I
10.1063/1.2399338
中图分类号
O59 [应用物理学];
学科分类号
摘要
The CaMgSi2O6:Eu2+, Mn2+ phosphors show three emission bands peaking at around 450 nm (blue), 580 nm (yellow), and 680 nm (red). The blue band originates from the allowed f-d transition of Eu2+ ions on Ca sites. The yellow and red bands originate from the forbidden T-4(1)-(6)A(1) transition of Mn2+ ions on Mg2+ and Ca2+ sites, respectively. Electron paramagnetic resonance measurement demonstrates that Mn2+ ions occupy two different Ca2+ and Mg2+ sites. The mixtures of the green-poor CaMgSi2O6:Eu2+, Mn2+ and the green-to-yellow emissive (Ba,Sr)(2)SiO4:Eu2+, excited by the near ultraviolet of 365 nm, show the various chromaticity of white light depending on the mixture ratio; the correlated color temperatures from 4845 to 9180 K, and the color rendering indices from 71% to 88%.
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页数:3
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