Synthesis and electrochemical properties of a new class of boron-containing n-type conjugated polymers

被引：46

作者：

Chai, Jianfang ^{[1
]}

Wang, Chao ^{[1
]}

Jia, Li ^{[1
]}

Pang, Yi ^{[2
]}

Graham, Matthew ^{[1
]}

Cheng, Stephen Z. D. ^{[1
]}

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

SYNTHETIC METALS | 2009年 / 159卷 / 14期

基金：

美国国家科学基金会;

关键词：

n-Type conjugated polymer; METAL-COMPLEXES; SOLAR-CELLS; DIBORAETHENE COMPOUNDS; PI-CONJUGATION; LEWIS-ACIDS; DERIVATIVES; LIGANDS; SYSTEMS; REDOX; 5,5'-BIS(DIMESITYLBORYL)-2,2'-BITHIOPHENE;

D O I：

10.1016/j.synthmet.2009.03.028

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Several electron-deficient polymers containing the 9,10-diboroanthracene unit have been synthesized and characterized. Electrochemical study shows that they have high electron affinities. Photoluminescence of rr-P3HT is quenched in the presence of one of the polymers in the solid state, demonstrating the potential utility of this class of polymer as powerful n-type materials in organic photovoltaic devices. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1443 / 1449

页数：7