Synthesis and applications of [Au(NCPh)(2)](+), a versatile labile gold(I) intermediate

被引：32

作者：

Yau, J ^{[1
]}

Mingos, DMP ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED, DEPT CHEM, LONDON SW7 2AY, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a606207e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Au(NCPh)(2)](+) cation has been isolated and synthesized in high yields by the oxidation of gold powder in the presence of NOBF4. It represents a labile form of gold(I), which has been shown to be a valuable synthon for the synthesis of a wide range of gold(I) complexes and especially of a variety of gold(I) amines which have opened new synthetic routes for the isolation of organometallic gold(I) complexes.

引用

页码：1103 / 1111

页数：9

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