Click-chemistry-based bis-triazolylpyridine diphosphonate ligand for the sensitized luminescence of lanthanides in the solid state within the layers of γ-zirconium phosphate

被引:25
作者
Brunet, Ernesto [1 ]
Juanes, Olga [1 ]
Jimenez, Laura [1 ]
Carlos Rodriguez-Ubis, Juan [1 ]
机构
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain
关键词
COMPLEXES; MOTIF;
D O I
10.1016/j.tetlet.2009.07.027
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis by means of 'click' chemistry of a new ligand bearing the bis-triazolylpyridine motif and pendant phosphonate groups is described. The topotactic phosphate/phosphonate exchange of the ligand into gamma-zirconium phosphate led to an organic-inorganic-layered material which revealed an excellent matrix to achieve the efficient sensitization of emitting lanthanides. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5361 / 5363
页数:3
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