A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4′-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer

被引：50

作者：

Yoneda, K

Adachi, K

Hayami, S

Maeda, Y

Katada, M

Fuyuhiro, A

Kawata, S ^{[1
]}

Kaizaki, S

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan

[2] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

[3] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 01期

关键词：

D O I：

10.1039/b512266j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The variable temperature magnetic susceptibility, X-ray crystallography, and Mossbauer and Raman spectra of a new dinuclear complex-based one-dimensional coordination polymer [{Fe-2(II)(NCS)(2)(mu-bpypz)(2)}(mu-4,4'-bpy)]center dot MeOH demonstrated a steep one-step [HS-HS] to [LS-LS] spin transition.

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收藏

页码：45 / 47

页数：3

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