Oxidative addition of N-H bonds to a metal center: Synthesis, characterization, and crystal structure of new rhodium(III) hydrido-pyrazolate complexes

被引：22

作者：

Ardizzoia, GA

Brenna, S

LaMonica, G

Maspero, A

Masciocchi, N

Moret, M

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Anali, I-20133 Milan, Italy

[2] Univ Milan, Ctr CNR, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[4] Univ Milano Bicocca, Dipartimento Sci Mat, I-20125 Milan, Italy

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 03期

关键词：

D O I：

10.1021/ic010852f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of pyrazoles easily react with [Rh(PPh3)(4)H], leading to hydrido-pyrazolate complexes through oxidative addition of N-H bonds to the metal center. The reaction products have been characterized by IR and multinuclear NMR spectroscopy and standard X-ray diffraction methods.

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页码：610 / +

页数：6

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