Ambient Fabrication of Large-Area Graphene Films via a Synchronous Reduction and Assembly Strategy

被引：194

作者：

Cao, Xuebo ^{[1
,2
]}

Qi, Dianpeng ^{[1
]}

Yin, Shengyan ^{[1
]}

Bu, Jing ^{[1
]}

Li, Fengji ^{[3
]}

Goh, Chin Foo ^{[1
]}

Zhang, Sam ^{[3
]}

Chen, Xiaodong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[3] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 21期

基金：

新加坡国家研究基金会;

关键词：

graphene films; large areas; ambient fabrication; self-assembly; redox reactions; ELECTRONIC MATERIAL; GRAPHITE OXIDE; SHEETS; TRANSPARENT; TRANSISTORS; SUPERCAPACITORS; PERFORMANCE; DEPOSITION; NANOSHEETS; EVOLUTION;

D O I：

10.1002/adma.201300586

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synchronous reduction and assembly strategy is designed to fabricate large-area graphene films and patterns with tunable transmittance and conductivity. Through an oxidation-reduction reaction between the metal substrate and graphene oxide, graphene oxide is reduced to chemically converted graphene and is organized into highly ordered films in situ. This work will form the precedent for industrial-scale production of graphene materials for future applications in electronics and optoelectronics. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2957 / 2962

页数：6

共 44 条

[21] Toward a Universal "Adhesive Nanosheet" for the Assembly of Multiple Nanoparticles Based on a Protein-Induced Reduction/Decoration of Graphene Oxide [J].

Liu, Jinbin ;

Fu, Songhe ;

Yuan, Bin ;

Li, Yulin ;

Deng, Zhaoxiang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (21) :7279-+

[22] Self-assembly of graphene oxide on the surface of aluminum foil [J].

Liu, Qingye ;

He, Meng ;

Xu, Xiaojuan ;

Zhang, Lina ;

Yu, Junping .

NEW JOURNAL OF CHEMISTRY, 2013, 37 (01) :181-187

[23] Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films [J].

Mattevi, Cecilia ;

Eda, Goki ;

Agnoli, Stefano ;

Miller, Steve ;

Mkhoyan, K. Andre ;

Celik, Ozgur ;

Mastrogiovanni, Daniel ;

Granozzi, Gaetano ;

Garfunkel, Eric ;

Chhowalla, Manish .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (16) :2577-2583

[24] Graphene Double-Layer Capacitor with ac Line-Filtering Performance [J].

Miller, John R. ;

Outlaw, R. A. ;

Holloway, B. C. .

SCIENCE, 2010, 329 (5999) :1637-1639

[25] Fine structure constant defines visual transparency of graphene [J].

Nair, R. R. ;

Blake, P. ;

Grigorenko, A. N. ;

Novoselov, K. S. ;

Booth, T. J. ;

Stauber, T. ;

Peres, N. M. R. ;

Geim, A. K. .

SCIENCE, 2008, 320 (5881) :1308-1308

[26] Unimpeded Permeation of Water Through Helium-Leak-Tight Graphene-Based Membranes [J].

Nair, R. R. ;

Wu, H. A. ;

Jayaram, P. N. ;

Grigorieva, I. V. ;

Geim, A. K. .

SCIENCE, 2012, 335 (6067) :442-444

[27] Highly Stretchable, Integrated Supercapacitors Based on Single-Walled Carbon Nanotube Films with Continuous Reticulate Architecture [J].

Niu, Zhiqiang ;

Dong, Haibo ;

Zhu, Bowen ;

Li, Jinzhu ;

Hng, Huey Hoon ;

Zhou, Weiya ;

Chen, Xiaodong ;

Xie, Sishen .

ADVANCED MATERIALS, 2013, 25 (07) :1058-1064

[28] Electrophoretic Build-Up of Alternately Multilayered Films and Micropatterns Based on Graphene Sheets and Nanoparticles and their Applications in Flexible Supercapacitors [J].

Niu, Zhiqiang ;

Du, Jianjun ;

Cao, Xuebo ;

Sun, Yinghui ;

Zhou, Weiya ;

Hng, Huey Hoon ;

Ma, Jan ;

Chen, Xiaodong ;

Xie, Sishen .

SMALL, 2012, 8 (20) :3201-3208

[29] A Leavening Strategy to Prepare Reduced Graphene Oxide Foams [J].

Niu, Zhiqiang ;

Chen, Jun ;

Hng, Huey Hoon ;

Ma, Jan ;

Chen, Xiaodong .

ADVANCED MATERIALS, 2012, 24 (30) :4144-4150

[30] Electric field effect in atomically thin carbon films [J].

Novoselov, KS ;

Geim, AK ;

Morozov, SV ;

Jiang, D ;

Zhang, Y ;

Dubonos, SV ;

Grigorieva, IV ;

Firsov, AA .

SCIENCE, 2004, 306 (5696) :666-669

← 1 2 3 4 5 →