Visible Light-Induced Aerobic Oxyamidation of Indoles: A Photocatalytic Strategy for the Preparation of Tetrahydro-5H-indolo[2,3-b]quinolinols

被引：47

作者：

An, Jing ^{[1
]}

Zou, You-Quan ^{[1
]}

Yang, Qing-Qing ^{[1
]}

Wang, Qiang ^{[1
]}

Xiao, Wen-Jing ^{[1
]}

机构：

[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 08期

基金：

美国国家科学基金会;

关键词：

aerobic oxidation; indoles; oxyamidation; visible light photocatalysis; PHOTOREDOX CATALYSIS; SINGLET OXYGEN; ORGANIC-SYNTHESIS; PHOTOSENSITIZED OXYGENATION; PENICILLIUM-EXPANSUM; TRYPTOPHAN; OXIDATION; FUNCTIONALIZATION; CYCLOADDITIONS; METABOLITES;

D O I：

10.1002/adsc.201300175

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A visible light-induced, aerobic oxyamidation reaction of indoles, using air as the sole oxidant, has been developed. This process serves as a photocatalytic strategy to generate efficiently tetrahydro-5H-indolo[2,3-b]quinolinols, which may have interesting biological and pharmacological activities owing to their privileged indoline structure.

引用

页码：1483 / 1489

页数：7

共 91 条

[1] A NEW METHOXYLATION OF 3-HYDROPEROXY INDOLINES FROM PHOTO-OXYGENATION OF INDOLES IN A REDUCING MEDIUM
AMSTERDAMSKY, C
RIGAUDY, J
[J]. TETRAHEDRON LETTERS, 1981, 22 (15) : 1403 - 1406
[2] Penicillium expansum:: Consistent production of patulin, chaetoglobosins, and other secondary metabolites in culture and their natural occurrence in fruit products
Andersen, B
Smedsgaard, J
Frisvad, JC
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2004, 52 (08) : 2421 - 2428
[3] [Anonymous], 2009, ANGEW CHEM INT ED, V48, P9785
[4] [Anonymous], 2003, ANGEW CHEM INT ED, V42, P577
[5] [Anonymous], 2010, ANGEW CHEM INT ED, V49, P1634
[6] [Anonymous], 2011, ANGEW CHEM INT ED, V50, P9655
[7] [Anonymous], 2012, ANGEW CHEM INT ED, V51, P4144
[8] [Anonymous], 2011, ANGEW CHEM INT ED, V50, P7171
[9] [Anonymous], 2011, ANGEW CHEM INT ED, V50, P657
[10] [Anonymous], 2012, ANGEW CHEM INT ED, V51, P784

← 1 2 3 4 5 6 7 8 9 10 →