First metal azide complex with isonicotinate as a bridging ligand showing new net topology: Hydrothermal synthesis, structure, and magnetic properties

被引：127

作者：

Liu, FC

Zeng, YF

Jiao, J

Bu, XH ^{[1
]}

Ribas, J

Batten, SR

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 07期

关键词：

D O I：

10.1021/ic051896h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D azido-bridged coordination polymer, [CO1.5(N-3)(OH)(Isonic)](n) (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.

引用

页码：2776 / 2778

页数：3

共 45 条

[41]

Rueff JM, 2001, EUR J INORG CHEM, P2843

[42]

Rueff JM, 2002, CHEM-EUR J, V8, P1813, DOI 10.1002/1521-3765(20020415)8:8<1813::AID-CHEM1813>3.0.CO

[43]

2-G

[44] Synthesis, structure and anion-exchange property of the first example of self-penetrated three-dimensional metal-organic framework with flexible three-connecting ligand and nickel(II) perchlorate [J].