Zn(tbip) (H2tbip=5-tert-butyl isophthalic acid):: A highly stable guest-free microporous metal organic framework with unique gas separation capability

被引：446

作者：

Pan, L ^{[1
]}

Parker, B ^{[1
]}

Huang, XY ^{[1
]}

Olson, DH ^{[1
]}

Lee, J ^{[1
]}

Li, J ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 13期

关键词：

D O I：

10.1021/ja057667b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 Å. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm). Copyright © 2006 American Chemical Society.

引用

页码：4180 / 4181

页数：2

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