Direct observation of hydrogen molecules adsorbed onto a microporous coordination polymer

被引:215
作者
Kubota, Y [1 ]
Takata, M
Matsuda, R
Kitaura, R
Kitagawa, S
Kato, K
Sakata, M
Kobayashi, TC
机构
[1] Osaka Womens Univ, Fac Sci, Dept Environm Sci, Sakai, Osaka 5900035, Japan
[2] Japan Synchrotron Radiat Res Inst, Sayogun, Hyogo 6795198, Japan
[3] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Kyoto 6158510, Japan
[4] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
[5] Okayama Univ, Dept Phys, Okayama 7008530, Japan
[6] Japan Sci & Technol Agcy, CREST, Tokyo, Japan
关键词
hydrogen adsorption; metal-organic frameworks; microporous materials; structure elucidation; X-ray diffraction;
D O I
10.1002/anie.200461895
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trapped hydrogen molecules in the nanochannels of a copper coordination polymer were successfully observed by the synchrotron powder-diffraction method. The adsorbed molecules are located near one corner of the rectangular nanochannels, and the pockets of the pore walls are suited to the size of the hydrogen molecules (see picture). These results could provide guidelines for the design of hydrogen-storage materials.
引用
收藏
页码:920 / 923
页数:4
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