Zinc(II) complexes of tetrapodal ligands derived from tetra-substituted 1,n-diaminoalcohols

被引：24

作者：

Adams, H ^{[1
]}

Bradshaw, D ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b110264h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dinuclear zinc(II) complexes have been prepared from one non-symmetric and two symmetric compartmental ligands in which the pendant arms, bearing pyridyl and phenolic functions, are bridged by spacers derived from 1,n-diaminoalcohols. The X-ray crystal structures of four complexes [Zn2L1(OAc)](ClO4)(2).CH3OH (1a), [Zn2L1(OAc)](BPh4)(2).6H(2)O (2a), [Zn2L2(OAc)](PF6)(2) (4a) and [Zn2L3(OAc)].2.5H(2)O.1.5CH(3)OH (8a) are reported.

引用

页码：925 / 930

页数：6

共 26 条

[11] SYNTHESIS, CHARACTERIZATION, AND REVERSIBLE OXYGENATION OF MU-ALKOXO DIIRON(II) COMPLEXES WITH THE DINUCLEATING LIGAND N,N,N',N'-TETRAKIS((6-METHYL-2-PYRIDYL)METHYL)-1,3-DIAMINOPROPAN-2-OLATE [J].

HAYASHI, Y ;

KAYATANI, T ;

SUGIMOTO, H ;

SUZUKI, M ;

INOMATA, K ;

UEHARA, A ;

MIZUTANI, Y ;

KITAGAWA, T ;

MAEDA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (45) :11220-11229

[12] HIGH-RESOLUTION (1.5 A) CRYSTAL-STRUCTURE OF PHOSPHOLIPASE-C FROM BACILLUS-CEREUS [J].

HOUGH, E ;

HANSEN, LK ;

BIRKNES, B ;

JYNGE, K ;

HANSEN, S ;

HORDVIK, A ;

LITTLE, C ;

DODSON, E ;

DEREWENDA, Z .

NATURE, 1989, 338 (6213) :357-360

[13] MU-PEROXO DICOBALT COMPLEXES CONTAINING AN UNSYMMETRICAL DINUCLEATING LIGAND - SYNTHESIS, CHARACTERIZATION, AND OXYGEN-AFFINITY [J].

KAYATANI, T ;

HAYASHI, Y ;

SUZUKI, M ;

UEHARA, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (11) :2980-2989

[14] MODEL COMPOUNDS FOR THE OXIDIZED UTEROFERRIN PHOSPHATE COMPLEX WITH NOVEL DINUCLEATING LIGANDS CONTAINING PHENOLATE AND PYRIDINE DONORS [J].

KREBS, B ;

SCHEPERS, K ;

BREMER, B ;

HENKEL, G ;

ALTHAUS, E ;

MULLERWARMUTH, W ;

GRIESAR, K ;

HAASE, W .

INORGANIC CHEMISTRY, 1994, 33 (09) :1907-1914

[15] ELECTRONIC-SPECTRA OF METAL-DIOXYGEN COMPLEXES [J].

LEVER, ABP ;

GRAY, HB .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (09) :348-355

[16] HEMOCYANIN MODELS - SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF A BINUCLEATING COPPER(II) SYSTEM [J].

MCKEE, V ;

ZVAGULIS, M ;

DAGDIGIAN, JV ;

PATCH, MG ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :4765-4772

[17] Crystal structure, spectral and magnetic properties of a new (μ-acetate)(μ-alkoxide) dicopper(II) complex as a model for tyrosinase [J].

Neves, A ;

Rossi, LM ;

Vencato, I ;

Drago, V ;

Haase, W ;

Werner, R .

INORGANICA CHIMICA ACTA, 1998, 281 (01) :111-115

[18] A NEW N,O-DONOR BINUCLEATING LIGAND AND ITS 1ST IRON(III) COMPLEX AS A MODEL FOR THE PURPLE ACID-PHOSPHATASES [J].

NEVES, A ;

ERTHAL, SMD ;

DRAGO, V ;

GRIESAR, K ;

HAASE, W .

INORGANICA CHIMICA ACTA, 1992, 197 (02) :121-124

[19]

SATO M, 1992, SYNTHESIS-STUTTGART, P539

[20] DINUCLEAR COBALT(II) COMPLEXES CONTAINING 1,3-(OR 1,5-)BIS[BIS-(2-PYRIDYLMETHYL)AMINO]-2-PROPANOLATO (OR -3-PENTANOLATO) - PREPARATION AND REACTION WITH MOLECULAR-OXYGEN [J].

SUZUKI, M ;

SUGISAWA, T ;

UEHARA, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (04) :1115-1120

← 1 2 3 →