Synthesis and crystal structure of highly soluble ansa-titano- and zirconocene dichloride complexes [Me2Si(η5-C5H2(SiMe3)2]2MCl2 (M = Ti, Zr)

被引：8

作者：

Douziech, B ^{[1
]}

Choukroun, R ^{[1
]}

Lorber, C ^{[1
]}

Donnadieu, B ^{[1
]}

机构：

[1] Chim Coordinat Lab, CNRS UPR 8241, F-31077 Toulouse 4, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 649卷 / 1-2期

关键词：

ansa-metallocene; zirconium; titanium; structure determination; electrochemistry;

D O I：

10.1016/S0022-328X(01)01437-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and X-ray characterization of ansa-metallocene dichloride titanium and zirconium complexes of the type [Me2Si(eta(5)-C5H2(SiMe3)(2))(2)]MCl2 (M = Zr (1), Ti (2)) are reported. The complexes have been tested for ethylene polymerization. (C) 2002 Published by Elsevier Science B.V.

引用

页码：15 / 20

页数：6

共 30 条

[1] Effect of the nature of metallocene complexes of group IV metals on their performance in catalytic ethylene and propylene polymerization [J].

Alt, HG ;

Köppl, A .

CHEMICAL REVIEWS, 2000, 100 (04) :1205-1221

[2] ansa-metallocene complexes of type (C13H8-SiR2-C9H6-nR′n)ZrCl2 (n = 0, 1, R = Me, Ph, alkenyl, R′ = alkyl, alkenyl):: self-immobilizing catalysts precursors for ethylene polymerization [J].

Alt, HG ;

Jung, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (02) :229-253

[3] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[4] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].

BRINTZINGER, HH ;

FISCHER, D ;

MULHAUPT, R ;

RIEGER, B ;

WAYMOUTH, RM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170

[5]

Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO

[6]

2-3

[7] Cocatalysts for metal-catalyzed olefin polymerization: Activators, activation processes, and structure-activity relationships [J].

Chen, EYX ;

Marks, TJ .

CHEMICAL REVIEWS, 2000, 100 (04) :1391-1434

[8] A ZIRCONIUM HYDRIDE ENOLATE FROM CARBONYLATION OF THE ALKYL COMPOUND [ZR(C5H2(SIME(3))(3)-1,2,4)(2)(ME)(2)] [J].

CHOUKROUN, R ;

DOUZIECH, B ;

SOLEIL, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :2017-2018

[9] STRUCTURE OF THE UNREACTIVE HINDERED CYCLOPENTADIENYLZIRCONIUM COMPOUND [C5H2(SIME3)3]2ZRCL2 [J].

CHOUKROUN, R ;

DAHAN, F .

ORGANOMETALLICS, 1994, 13 (05) :2097-2100

[10] Precise control of polyolefin stereochemistry using single-site metal catalysts [J].

Coates, GW .

CHEMICAL REVIEWS, 2000, 100 (04) :1223-1252

← 1 2 3 →