Scintillating Metal-Organic Frameworks: A New Class of Radiation Detection Materials

被引：155

作者：

Doty, F. P. ^{[1
]}

Bauer, C. A. ^{[1
]}

Skulan, A. J. ^{[1
]}

Grant, P. G. ^{[2
]}

Allendorf, M. D. ^{[1
]}

机构：

[1] Sandia Natl Labs, Livermore, CA 94551 USA

[2] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 01期

基金：

美国国家科学基金会;

关键词：

BEAM-INDUCED LUMINESCENCE; SELECTIVE SORPTION; MICROPOROUS METAL; HYDROGEN STORAGE; DESIGN; STILBENE; TRANS; ZINC; FLUORESCENCE; ABSORPTION;

D O I：

10.1002/adma.200801753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks containing an organic fluorophore such as stilbene dicarboxylate emit prompt visible light when they interact with ionizing radiation (e.g., high-energy protons or alpha particles). A completely new class of scintillation materials is created by this development, with the potential to rationally tailor properties for specific radiation detection applications.

引用

收藏

页码：95 / 101

页数：7

相关论文

共 45 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].

Alaerts, Luc ;

Seguin, Etienne ;

Poelman, Hilde ;

Thibault-Starzyk, Frederic ;

Jacobs, Pierre A. ;

De Vos, Dirk E. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (28) :7353-7363

[2]

[Anonymous], 2017, J MOL STRUCT, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014

[3] FORMATION OF DIMER CATIONS OF AROMATIC HYDROCARBONS [J].

BADGER, B ;

BROCKLEH.B .

NATURE, 1968, 219 (5151) :263-&

[4] Porous material for absorption and luminescent detection of aromatic molecules in water [J].

Bai, Y ;

He, GJ ;

Zhao, YG ;

Duan, CY ;

Dang, DB ;

Meng, QJ .

CHEMICAL COMMUNICATIONS, 2006, (14) :1530-1532

[5] Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks [J].

Bauer, Christina A. ;

Timofeeva, Tatiana V. ;

Settersten, Thomas B. ;

Patterson, Brian D. ;

Liu, Vincent H. ;

Simmons, Blake A. ;

Allendorf, Mark D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7136-7144

[6] Stilbenoid dimers: Dissection of a paracyclophane chromophore [J].

Bazan, GC ;

Oldham, WJ ;

Lachicotte, RJ ;

Tretiak, S ;

Chernyak, V ;

Mukamel, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (36) :9188-9204

[7]

Birks J. B., 1964, THEORY PRACTICE SCIN, DOI [DOI 10.1016/C2013-0-01791-4, 10.1016/C2013-0-01791-4]

[8] EXCIMERS [J].

BIRKS, JB .

REPORTS ON PROGRESS IN PHYSICS, 1975, 38 (08) :903-974

[9] Luminescent zinc and cadmium complexes incorporating 1,3,5-benzenetricarboxylate and a protonated kinked organodiimine: From a hydrogen-bonded layer motif to thermally robust two-dimensional coordination polymers [J].

Braverman, Maxwell A. ;

Supkowski, Ronald M. ;

LaDuca, Robert L. .

JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (06) :1852-1862

[10] Ion beam induced luminescence of materials [J].

Brooks, RJ ;

Hole, DE ;

Townsend, PD .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2002, 190 :136-140

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