Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile;: X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl•MeCN

被引：27

作者：

Kelly, PF ^{[1
]}

Slawin, AMZ ^{[1
]}

机构：

[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 12期

关键词：

D O I：

10.1039/a901783f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)(2)Cl-2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)CI]Cl . MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.

引用

页码：1081 / 1082

页数：2

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