Microwave spectrum up to 900 GHz of SO created in highly excited states by electric discharge and UV-laser photolysis

被引：55

作者：

Bogey, M

Civis, S

Delcroix, B

Demuynck, C

Krupnov, AF

Quiguer, J

Tretyakov, MY

Walters, A

机构：

[1] ACAD SCI CZECH REPUBL,J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CR-18223 PRAGUE 8,CZECH REPUBLIC

[2] RUSSIAN ACAD SCI,INST PHYS APPL,NIZHNII NOVGOROD 603600,RUSSIA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1997年 / 182卷 / 01期

关键词：

D O I：

10.1006/jmsp.1996.7218

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

SO was created by electric discharge in a mixture of SO2 and Ar and by UV-laser photolysis of Cl2SO. The two methods are compared. The pure rotational spectrum of the X(3) Sigma(-) electronic ground state was measured in highly excited vibrational states up to v = 17, that of the a(1) Delta excited state up to v = 13, and that of the b(1) Sigma(+) excited state up to v = 11. Measurements up to 900 GHz without harmonic generation were possible thanks to the use of Russian-constructed BWOs. (C) 1997 Academic Press.

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页码：85 / 97

页数：13

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