A homoleptic cuprate(II) complex with deprotonated 1,6-anhydro-beta-D-glucose (levoglucosan) ligands

被引：11

作者：

Gack, C

Klufers, P

机构：

[1] Inst. F. Anorganische Chem. Univ., D-76128 Karlsruhe, Engesserstraße

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S010827019600947X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cuprate anion in the title complex, dilithium bis[1,6-anhydro-beta-D-glucosidato(2-)-O-2,O-4]cuprate(II) octahydrate, Li-2[Cu(C6H8O5)(2)].8H(2)O, is a homoleptic mononuclear 1,3-polyolato(2-) complex. The ligator atoms of the levoglucosan ligand are closer together by ca 0.4 Angstrom with respect to the uncomplexed 1,3-diol moiety of the anhydro suger, thus exhibiting an enhanced flexibility compared with 1,2-diols.

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页码：2972 / 2975

页数：4

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