The sodium salt of N1-deprotonated inosine, Na+.C10H11N4O5-.2.5H(2)O

被引：4

作者：

Klufers, P

Mayer, P

机构：

[1] Inst. F. Anorganische Chem. Univ., D-76128 Karlsruhe, Engesserstraße

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196009043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, sodium inosinate(1-)-water (1/2.5), Na(inosineH(-1)).2.51-H2O, crystallizes from aqueous alkaline solution. Each N1-deprotonated monoanion has a syn conformation which is stabilized by intramolecular O5'-H ... N3 hydrogen bonds. Face-shared pentaaqua-disodium dications bind to ribose O2' and O5' atoms, but are not ligated by the hypoxanthine moiety.

引用

页码：2970 / 2972

页数：3

共 16 条

[1] SYNTHESIS, FT-IR AND H-1-NMR STUDIES OF ALKALI AND ALKALINE-EARTH METAL-COMPLEXES WITH GUANOSINE [J].

BARIYANGA, J ;

THEOPHANIDES, T .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1985, 108 (02) :133-140

[2] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[3] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[4]

Johnson C. K., 1976, ORNL5138

[5] BINDING-SITES AND STABILITIES OF TRANSITION-METAL IONS WITH NUCLEOSIDES AND RELATED LIGANDS [J].

KIM, SH ;

MARTIN, RB .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1984, 91 (01) :19-24

[6] POLYOL METAL-COMPLEXES .13. NA-2[BE(C4H6O3)(2)]CENTER-DOT-5H(2)O AND NA-2[PB(C4H6O3)(2)]CENTER-DOT-3H(2)O - 2 HOMOLEPTIC BIS POLYOLATO METALLATES WITH BERYLLIUM AND WITH LEAD [J].

KLUFERS, P ;

MAYER, P ;

SCHUHMACHER, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (08) :1373-1379

[7]

KLUFERS P, 1996, IN PRESS Z ANORG ALL

[8]

LONNBERG H, 1990, P284

[9] CRYSTAL AND MOLECULAR STRUCTURE OF INOSINE [J].

MUNNS, ARI ;

TOLLIN, P .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 :1101-&

[10]

Sheldrick G. M., 1985, SHELXS86 PROGRAM SOL

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