POLYOL METAL-COMPLEXES .13. NA-2[BE(C4H6O3)(2)]CENTER-DOT-5H(2)O AND NA-2[PB(C4H6O3)(2)]CENTER-DOT-3H(2)O - 2 HOMOLEPTIC BIS POLYOLATO METALLATES WITH BERYLLIUM AND WITH LEAD

被引：21

作者：

KLUFERS, P

MAYER, P

SCHUHMACHER, J

机构：

[1] Institut Für Anorganische Chemie, Universität Engesserstraße, Karlsruhe, 76128

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 08期

关键词：

DIANIONIC POLYOLATO LIGANDS; DEPROTONATED ANHYDROERYTHRITOL; BERYLLIUM; LEAD; CRYSTAL STRUCTURES;

D O I：

10.1002/zaac.19956210816

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Na-2[Be(C4H6O3)(2)] . 5 H2O (1) and Na-2[Pb(C4H6O3)(2)] . 3 H2O (2) crystallize from concentrated, alkaline aqueous solutions. The polyol anhydroerythritol is deprotonated twice in the mononuclear, homoleptic complex anions. The preference of beryllium for the binding of cis-furanoid diols is shown. In 2, a stereochemically active lone pair at the central atom is the reason for the construction of low dimensional aggregates from three plumbate and three sodium ions.

引用

页码：1373 / 1379

页数：7

共 15 条

[1] POLYOL METAL-COMPLEXES .12. SYNTHESIS AND STRUCTURE OF COBALT(III) COMPLEXES WITH DOUBLY DEPROTONATED ANHYDROERYTHRITOL, METHYL ALPHA-D-MANNOPYRANOSIDE, AND METHYL BETA-D-GALACTOPYRANOSIDE [J].