Regiochemistry of molybdenum-catalyzed O-H insertions of vinylcarbenoids

被引：25

作者：

Davies, HML ^{[1
]}

Yokota, Y ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 25期

基金：

美国国家科学基金会;

关键词：

carbenes and carbenoids; diazo compounds; O-H insertion; molybdenum; rhodium;

D O I：

10.1016/S0040-4039(00)00745-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Molybdenum-catalyzed decomposition of vinyldiazoacetates generates vinylcarbenoids that preferentially react with alcohols at the vinylogous position of the vinylcarbenoid rather than at the carbenoid site. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4851 / 4854

页数：4

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