Solution synthesis of Cu2O/TiO2 core-shell nanocomposites

被引：45

作者：

Su, Xiaodan ^{[1
,2
]}

Zhao, Jingzhe ^{[1
]}

Li, Yunling ^{[1
,2
]}

Zhu, Yanchao ^{[2
]}

Ma, Xiaokun ^{[2
]}

Sun, Fang ^{[2
]}

Wang, Zichen ^{[2
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China

[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2009年 / 349卷 / 1-3期

关键词：

Cu2O; TiO2; Nanocomposites; Core-shell structure; Photo-electrical properties; Hydrolyzation; CUPROUS-OXIDE; NANOPARTICLES; TIO2; FILM; NANOSTRUCTURES; NANOWIRES; OXIDATION; ROUTE;

D O I：

10.1016/j.colsurfa.2009.08.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report here a simple approach to the synthesis of Cu2O/TiO2 core-shell nanocomposites with uniform octahedral structure in solution phase. First, fresh synthesized Cu2O octahedra were used as precursor, and butyl titanate (Ti(OBu)(4)) diluted by ethanol was preliminary hydrolyzed by the water adsorbed on the surface of Cu2O, so a very thin TiO2 condensed on the Cu2O surfaces. Then, when a mixture of water and ethanol was dropped into the reaction system, the Ti(OBu)(4) would further hydrolyze and condense around the Cu2O to form TiO2, so octahedral Cu2O/TiO2 core-shell composites with uniform and compact TiO2 shells were obtained. This method is suitable for the formation of uniform integrated TiO2 shells and their thickness can be controlled by adjusting the ratio of water/ethanol (W/E). According to the surface photovoltage spectroscopy of the Cu2O/TiO2 composites, we think the material would have a potential application in photocatalysis and photoelectric transition. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：151 / 155

页数：5

共 30 条

[21] A facile synthesis of Cu2O/SiO2 and Cu/SiO2 core-shell octahedral nanocomposites [J].

Su, Xiaodan ;

Zhao, Jingzhe ;

Zhao, Xu ;

Guo, Yupeng ;

Zhu, Yanchao ;

Wang, Zichen .

NANOTECHNOLOGY, 2008, 19 (36)

[22] Controlled crystallization of nanoporous and core/shell structure titania photocatalyst particles [J].

Sung, YM ;

Lee, JK ;

Chae, WS .

CRYSTAL GROWTH & DESIGN, 2006, 6 (04) :805-808

[23] TWo-step solochemical synthesis of ZnO/TiO2 nano-composite materials [J].

Vaezi, M. R. .

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2008, 205 (1-3) :332-337

[24] Effect of surface species on Cu-TiO2 photocatalytic activity [J].

Xin, Baifu ;

Wang, Peng ;

Ding, Dandan ;

Liu, Jia ;

Ren, Zhiyu ;

Fu, Honggang .

APPLIED SURFACE SCIENCE, 2008, 254 (09) :2569-2574

[25] Preparation and characterization of Cu2O-TiO2: Efficient photocatalytic degradation of methylene blue [J].

Xu, Yue-hua ;

Liang, Da-hui ;

Liu, Man-le ;

Liu, Ding-zhong .

MATERIALS RESEARCH BULLETIN, 2008, 43 (12) :3474-3482

[26] Morphosynthesis of rhombododecahedral silver cages by self-assembly coupled with precursor crystal templating [J].

Yang, JH ;

Qi, LM ;

Lu, CH ;

Ma, JM ;

Cheng, HM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (04) :598-603

[27] Synthesis of novel core-shell structured WO3/TiO2 spheroids and its application in the catalytic oxidation of cyclopentene to glutaraldehyde by aqueous H2O2 [J].

Yang, XL ;

Dai, WL ;

Guo, CW ;

Chen, H ;

Cao, Y ;

Li, HX ;

He, HY ;

Fan, KN .

JOURNAL OF CATALYSIS, 2005, 234 (02) :438-450

[28] Multi-electron storage of photoenergy using Cu2O-TiO2 thin film photocatalyst [J].

Yasomanee, J. P. ;

Bandara, J. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (03) :348-352

[29] In situ Fenton reagent generated from TiO2/Cu2O composite film:: A new way to utilize TiO2 under visible light irradiation [J].

Zhang, Yong-Gang ;

Ma, Li-Li ;

Li, Jia-Lin ;

Yu, Ying .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (17) :6264-6269

[30] Synthesis and catalytic performance of TiO2 nanotubes-supported copper oxide for low-temperature CO oxidation [J].

Zhu, Baolin ;

Zhang, Xiaoxiang ;

Wang, Shurong ;

Zhang, Shoumin ;

Wu, Shihua ;

Huang, Weiping .

MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 102 (1-3) :333-336

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