Supramolecular-Directed Chiral Induction in Biaryl Derivatives

被引：24

作者：

Etxebarria, J. ^{[1
]}

Degenbeck, H. ^{[1
]}

Felten, A. -S. ^{[1
]}

Serres, S. ^{[1
]}

Nieto, N. ^{[1
]}

Vidal-Ferran, A. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 22期

关键词：

HYDROGEN-BONDING INTERACTIONS; PROTON-TRANSFER; AXIAL CHIRALITY; PARA-NITROPHENOL; DENSITY FUNCTIONALS; BONDED COMPLEXES; AMINE COMPLEXES; MESO LIGANDS; PHENOL; EQUILIBRIUM;

D O I：

10.1021/jo9015425

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A thermodynamically controlled resolution has allowed for the generation of diastereomerically enriched complexes, by chirality transfer from ail enantiopure building block to a dynamically racemic biaryl derivative. A switchable sense of induction could be achieved depending on the substituents of the chiral block.

引用

页码：8794 / 8797

页数：4

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